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DEET-based bug sprays, such as Off, won't technically expire but may become less effective over time. The same goes for bug sprays that use picaridin, oil of lemon eucalyptus, or para-menthane-3,8-diol. But if the active ingredient in your bug spray is ethyl butyl acetylamino propionate, commonly known as IR3535, it may expire within 18 months.
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